Data

Character table:

Nitride character Table

  TiN ZrN NbN TaN Cr2N VN
Nitrogen content[%] 22.63 13.31 13.10 7.19 11.87 21.56
Crystal structure Cubic Cubic Hexagonal Hexagonal Hexagonal Cubic
Lattice periods,kx. a 4.249 4.537 2.959 2.933 4.806 4.136
c     11.271 2.864 4.479  
c/a     3.804 0.98 0.928  
Density[g/cm3]
calculated
5.44 7.35 8.305 14.36 6.51 6.102
experimental 5.43 7.09 8.40 13.80   6.04
Microhardness 100g
[kg/mm2]
2050 1670 1461 1060 1571 1310
Melting Point[℃] 2950 2980 2300 3087 1650(分解) 2050
Heat of formation
ΔH°(298)[Kcal/mol]
-80.4 -87.3 -56.8±1.5 -59.0 -25.2 -60.0
Entropy S°(298)
[Kcal/mol・℃]
7.24±0.1 9.3±0.1 10.5±0.2 12.2±1.0 18.0±2.0 8.9±0.1
Specific electrical
resistance[μΩ・cm] at
20℃
40 18 54 198 84 60
Point of transition to
superconductivity  °K
5.6 9.8 <1.94 <4.2   8.2

(Reference) Hand book refractory compounds (metallurgiya in Moscow 1976 editions)

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